Semiconductor copper(II) macrocyclic complexes. Synthesis, characterization and electrical properties of copper(II) complexes (see abstract)

Armando Ortíz-rebollo; VerÓNica García-montalvo; Jacobo Gómez-lara; M. Elena Sánchez-vergara

doi:10.1080/00958970108022655

Semiconductor copper(II) macrocyclic complexes. Synthesis, characterization and electrical properties of copper(II) complexes (see abstract)

Armando Ortíz-rebollo, VerÓNica García-montalvo, Jacobo Gómez-lara, M. Elena Sánchez-vergara

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The complexes [Cu(TAABNH(CH₂)₂NH₂)](NO₃) ·2H₂O, (1) [Cu(TAABNH(CH₂)₄NH₂)] (NO₃)·4H₂O, (2), [Cu(TAABNH(CH₂)₁₂NH₂](NO₃) ·4H₂O, (3) and [Cu(TAAB(C₁₄H₁₀ N₂O₂)₂]·4H₂O, (4) have been synthesized and characterized by IR, mass spectroscopy, electronic spectroscopy, thermogravimetric analysis and elemental analysis. Electrical conductivity and activation energy evaluation were obtained from study of the temperature dependence of the electrical current (in tablet and thin film). Refraction and reflectance indices, absorption coefficient and optical activation energy were established through ellipsometry and UV-Vis spectroscopy. The electrical conductivity values at room temperature were within the range of semiconducting molecular solids (10^-6 - 10¹ω^-1cm^-1).

Original language	English
Pages (from-to)	441-453
Number of pages	13
Journal	Journal of Coordination Chemistry
Volume	54
Issue number	3-4
DOIs	https://doi.org/10.1080/00958970108022655
State	Published - 1 Jan 2001
Externally published	Yes

Keywords

Copper(II)
Macrocycles
Semiconductors

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10.1080/00958970108022655

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title = "Semiconductor copper(II) macrocyclic complexes. Synthesis, characterization and electrical properties of copper(II) complexes (see abstract)",

abstract = "The complexes [Cu(TAABNH(CH2)2NH2)](NO3) ·2H2O, (1) [Cu(TAABNH(CH2)4NH2)] (NO3)·4H2O, (2), [Cu(TAABNH(CH2)12NH2](NO3) ·4H2O, (3) and [Cu(TAAB(C14H10 N2O2)2]·4H2O, (4) have been synthesized and characterized by IR, mass spectroscopy, electronic spectroscopy, thermogravimetric analysis and elemental analysis. Electrical conductivity and activation energy evaluation were obtained from study of the temperature dependence of the electrical current (in tablet and thin film). Refraction and reflectance indices, absorption coefficient and optical activation energy were established through ellipsometry and UV-Vis spectroscopy. The electrical conductivity values at room temperature were within the range of semiconducting molecular solids (10-6 - 101ω-1cm-1).",

keywords = "Copper(II), Macrocycles, Semiconductors",

author = "Armando Ort{\'i}z-rebollo and Ver{\'O}Nica Garc{\'i}a-montalvo and Jacobo G{\'o}mez-lara and S{\'a}nchez-vergara, {M. Elena}",

year = "2001",

month = jan,

day = "1",

doi = "10.1080/00958970108022655",

language = "Ingl{\'e}s",

volume = "54",

pages = "441--453",

journal = "Journal of Coordination Chemistry",

issn = "0095-8972",

publisher = "Taylor and Francis Ltd.",

number = "3-4",

}

Semiconductor copper(II) macrocyclic complexes. Synthesis, characterization and electrical properties of copper(II) complexes (see abstract). / Ortíz-rebollo, Armando; García-montalvo, VerÓNica; Gómez-lara, Jacobo et al.
In: Journal of Coordination Chemistry, Vol. 54, No. 3-4, 01.01.2001, p. 441-453.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Semiconductor copper(II) macrocyclic complexes. Synthesis, characterization and electrical properties of copper(II) complexes (see abstract)

AU - Ortíz-rebollo, Armando

AU - García-montalvo, VerÓNica

AU - Gómez-lara, Jacobo

AU - Sánchez-vergara, M. Elena

PY - 2001/1/1

Y1 - 2001/1/1

N2 - The complexes [Cu(TAABNH(CH2)2NH2)](NO3) ·2H2O, (1) [Cu(TAABNH(CH2)4NH2)] (NO3)·4H2O, (2), [Cu(TAABNH(CH2)12NH2](NO3) ·4H2O, (3) and [Cu(TAAB(C14H10 N2O2)2]·4H2O, (4) have been synthesized and characterized by IR, mass spectroscopy, electronic spectroscopy, thermogravimetric analysis and elemental analysis. Electrical conductivity and activation energy evaluation were obtained from study of the temperature dependence of the electrical current (in tablet and thin film). Refraction and reflectance indices, absorption coefficient and optical activation energy were established through ellipsometry and UV-Vis spectroscopy. The electrical conductivity values at room temperature were within the range of semiconducting molecular solids (10-6 - 101ω-1cm-1).

AB - The complexes [Cu(TAABNH(CH2)2NH2)](NO3) ·2H2O, (1) [Cu(TAABNH(CH2)4NH2)] (NO3)·4H2O, (2), [Cu(TAABNH(CH2)12NH2](NO3) ·4H2O, (3) and [Cu(TAAB(C14H10 N2O2)2]·4H2O, (4) have been synthesized and characterized by IR, mass spectroscopy, electronic spectroscopy, thermogravimetric analysis and elemental analysis. Electrical conductivity and activation energy evaluation were obtained from study of the temperature dependence of the electrical current (in tablet and thin film). Refraction and reflectance indices, absorption coefficient and optical activation energy were established through ellipsometry and UV-Vis spectroscopy. The electrical conductivity values at room temperature were within the range of semiconducting molecular solids (10-6 - 101ω-1cm-1).

KW - Copper(II)

KW - Macrocycles

KW - Semiconductors

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U2 - 10.1080/00958970108022655

DO - 10.1080/00958970108022655

M3 - Artículo

AN - SCOPUS:0035759585

SN - 0095-8972

VL - 54

SP - 441

EP - 453

JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

IS - 3-4

ER -

Semiconductor copper(II) macrocyclic complexes. Synthesis, characterization and electrical properties of copper(II) complexes (see abstract)

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